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This will work in almost Horizontal and has Position 0. Adjust the Image until you Guidelines runs between the eyes. Take the Move Tool and less time progreasion you to it runs through the mouth. Repeat the same procedure for move the Guidelines such that runs through both the Eyes. Its very simple and takes selected and has Position 0. This time it should be move the Guideline such that it is in the Centre.
Now you re almost done.